A phosphine-mediated conversion of azides into diazo compounds.
نویسندگان
چکیده
N2 the mild: Diazo compounds are extremely versatile intermediates for synthetic organic chemistry, but their synthesis can be challenging in the presence of delicate functional groups. The Staudinger ligation has inspired a mild method for the conversion of a broad range of azides into their diazo compound derivatives through an acyl triazene intermediate.
منابع مشابه
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 48 13 شماره
صفحات -
تاریخ انتشار 2009